CATALYTIC OXIDATION BY MEANS OF COMPLEX IRON SALTS
نویسندگان
چکیده
منابع مشابه
Catalytic Oxidation by Means of Complex Iron
The observation of Manchot? that sodium pentacyano-ammineferroate2 I absorbs oxygen has led Baudisch and his coworkers3 to study the catalytic action of this salt, as well as of its water analogue II, in the oxidation of pyrimidines and purines. The present authors have previously reported in this journal4 on the nature of the oxidation products obtained. In the present paper the problem is con...
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We have used dioxygen, not artificial oxidants such as peracids, iodosylarenes, and hydroperoxides, in the generation of a mononuclear nonheme oxoiron(IV) complex, [Fe(IV)(TMC)(O)]2+ (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane), from its corresponding Fe(II) complex, [Fe(TMC)(CF3SO3)2]. The formation of oxoiron(IV) species by activating dioxygen was markedly dependent on iron(...
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ژورنال
عنوان ژورنال: Journal of Biological Chemistry
سال: 1927
ISSN: 0021-9258
DOI: 10.1016/s0021-9258(18)84436-2